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Le Chatelier's Principle Question?

This is what I wrote for a chemistry lab exam is it right? If not, where are the mistakes?

Main equilibrium: CrO4[2-] + H[+] <-> H2CrO4

Stress A: Add BaCl2

Secondary Eqm: H[+] + Cl[-] -> HCl

The equilibrium will shift to the left to produce the H+ ions.

Stress B: Add NaOH to the same well (meaning to the main eqm, add BaCl2 first and then add NaOH to that)

CrO4 + H <-> H2CrO4

H + Cl -> HCl

NaOH + H2CrO4 <-> H2O + Na2CrO4

As the H2CrO4 is used up, the eqm will shift towards the right.

I'm pretty sure a lot is wrong, but what is and what are the correct answers?

1 Answer

Relevance
  • Anonymous
    1 decade ago
    Favorite Answer

    Barium chromate percipitates out

    BaCl2 added

    makes Ba+2

    Ba+2 + CrO4-2 ---> BaCrO4

    thus rnx shifts to right to make more CrO4-- to replace the ones percicpitated

    -----

    OH- neuttralizes H+

    OH- + H+ --->H2O

    thus adding OH- shifts rnx back to the left

    Source(s): Soc
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